|本期目录/Table of Contents|

[1]范钊.黄河流域农田土壤有机氯农药残留污染特征研究[J].江苏农业科学,2016,44(05):414-419.
 Fan Zhao.Residual pollution characteristics of organochlorine pesticides in farmland soils in the Yellow River Basin[J].Jiangsu Agricultural Sciences,2016,44(05):414-419.
点击复制

黄河流域农田土壤有机氯农药残留污染特征研究(PDF)
分享到:

《江苏农业科学》[ISSN:1002-1302/CN:32-1214/S]

卷:
第44卷
期数:
2016年05期
页码:
414-419
栏目:
资源与环境
出版日期:
2016-05-25

文章信息/Info

Title:
Residual pollution characteristics of organochlorine pesticides in farmland soils in the Yellow River Basin
作者:
范钊
河南教育学院人口与生命科学系,河南郑州 450046
Author(s):
Fan Zhao
关键词:
黄河流域农田土壤有机氯农药残留
Keywords:
-
分类号:
X53
DOI:
-
文献标志码:
A
摘要:
采用现场采样与室内分析相结合的方法,利用气相色谱仪测定了黄河流域农田土壤有机氯农药(OCPs)残留物组成。结果表明:黄河流域农田土壤中残留有机氯农药主要是六六六(HCHs)、滴滴涕(DDTs)和六氯苯(HCB),其中HCHs是土壤残留有机氯农药类的主要成分。氯丹(TC+CC)、九氯(TN+CN)、硫丹(α-End+β-End)残留量较低,是黄河流域农田土壤中普遍存在的一类持久性有机污染物。土壤OCPs农药均随土层深度的增加而急剧降低,并且随深度的增加其降低幅度逐渐增加,垂直分布表现出明显的“表聚性”;不同土地利用类型OCPs农药含量基本为水田>菜地>耕地>林地,并且相同土层OCPs农药含量基本表现为水田>菜地>耕地>林地,其中CC和β-End在不同类型农田土壤中差异均不显著。土壤DDTs含量平均值顺序基本表现为o,p′-DDT>p,p′-DDT>p,p′-DDD,o,p′-DDT是DDT类污染物的主体物质;DDT/(DDD+DDE)均大于1,说明黄河流域农田土壤的DDT降解程度低。土壤HCH含量基本表现为β-HCH>γ-HCH> α-HCH>δ-HCH,其中α-HCH和β-HCH所占比例相对较高,具有较高的潜在危害性;菜地和耕地土壤α-HCH/γ-HCH比值小于1,说明菜地和耕地土壤中HCH同系物之间发生相互转化,存在较多的γ-HCH残留。主成分分析结果显示α-HCH、β-HCH、γ-HCH和δ-HCH在第1主成分上有较高载荷;DDTs类物质在第2主成分上有较高载荷;TC和CC、α-End和β-End、TN和CN在第3主成分上有较高载荷。Pearson相关分析表明,TOC与HCHs、HCB、OCPs呈极显著正相关(P<0.01),与α-End和β-End呈显著正相关(P<0.05),与DDTs相关性不显著,说明黄河流域农田土壤HCHs、HCB含量在很大程度上受TOC影响,HCHs与HCB、DDTs,HCB、DDTs与九氯(TN+CN)类农药的分布机制和输入来源可能相一致,在决定有机氯农药含量和分布上起着重要的作用。
Abstract:
-

参考文献/References:

[1]Zacharis C K,Rotsias I,Zachariadis P G,et al. Dispersive liquid-liquid microextraction for the determination of organochlorine pesticides residues in honey by gas chromatography-electron capture and ion trap mass spectrometric detection[J]. Food Chemistry,2012,134(3):1665-1672.
[2]Waliszewski S M,Caba M,Rodríguez Díaz S S,et al. Levels of organochlorine pesticides residues in human adipose tissue,data from Tabasco,Mexico[J]. Bulletin of Environmental Contamination and Toxicology,2012,89(5):1062-1067.
[3]Sojinu O S,Sonibare O O,Ekundayo Olusegun O,et al. Assessment of organochlorine pesticides residues in higher plants from oil exploration areas of Niger Delta,Nigeria[J]. Science of the Total Environment,2012,433:169-177.
[4]Bempah C K,Buah-Kwofie A,Enimil E,et al. Residues of organochlorine pesticides in vegetables marketed in Greater Accra Region of Ghana[J]. Food Control,2012,25(2):537-542.
[5]Choi J Y,Yang D B,Hong G H,et al. Distribution and bioaccumulation of polychlorinated biphenyls and organochlorine pesticides residues in sediments and Manila clams (Ruditapes philippinarum) from along the Mid-Western coast of Korea[J]. Marine Pollution Bulletin,2014,85(2):672-678.
[6]Wong F,Kurt-Karakus P,Bidleman T F. Fate of brominated flame retardants and organochlorine pesticides in urban soil:volatility and degradation[J]. Environmental Science & Technology,2012,46(5):2668-2674.
[7]Mishra K,Sharma R C,Kumar S. Contamination levels and spatial distribution of organochlorine pesticides in soils from India[J]. Ecotoxicology and Environmental Safety,2012,76(2):215-225.
[8]岳强,管玉峰,涂秀云,等. 广东北江上游流域农田土壤有机氯农药残留及其分布特征[J]. 生态环境学报,2012,21(2):321-326.
[9]瞿程凯,祁士华,张莉,等. 福建戴云山脉土壤有机氯农药残留及空间分布特征[J]. 环境科学,2013,34(11):4427-4433.
[10]崔健,王晓光,都基众,等. 沈阳郊区表层土壤有机氯农药残留特征及风险评价[J]. 中国地质,2014,41(5):1705-1715.
[11]迭庆杞,聂志强,黄启飞,等. 珠江三角洲土壤中有机氯农药的分布特征[J]. 农业环境科学学报,2014,33(2):298-304.
[12]岳强,管玉峰,涂秀云,等. 广东北江上游流域农田土壤有机氯农药残留及其分布特征[J]. 生态环境学报,2012,21(2):321-326.
[13]瞿程凯,祁士华,张莉,等. 福建戴云山脉土壤有机氯农药残留及空间分布特征[J]. 环境科学,2013,34(11):4427-4433.
[14]裴绍峰,刘海月,叶思源. 我国南方主要城市土壤有机氯农药残留及分布特征[J]. 山东农业大学学报:自然科学版,2014,45(5):768-774.
[15]穆季平. 持久性有机污染物(POPs)研究进展[J]. 环境科学与技术,2006,29(z1):140-143.
[16]李敬光,赵云峰,吴永宁. 我国持久性有机污染物人体负荷研究进展[J]. 环境化学,2011,30(1):5-19.
[17]Katayama A,Matsumura F. Degradation of organochlorine pesticides,particularly endosulfan,by Trichoderma harzianum[J]. Environmental Toxicology and Chemistry,1993,12(6):1059-1065.
[18]Yu Binbin,Zeng Jingbin,Gong Lifen,et al. Investigation of the photocatalytic degradation of organochlorine pesticides on a nano-TiO2 coated film[J]. Talanta,2007,72(5):1667-1674.
[19]Aigner E J,Leone A D,Falconer R L. Concentrations and enantiomeric ratios of organochlorine pesticides in soil from the US Corn Belt[J]. Environmental Science & Technology,1998,32(9):1162-1168.
[20]Miglioranza K,Aizpún de Moreno J E,Moreno V J,et al. Fate of organochlorine pesticides in soils and terrestrial biota of “Los Padres” pond watershed,Argentina[J]. Environmental Pollution,1999,105(1):91-99.
[21]Abou-Arab A K. Degradation of organochlorine pesticides by meat starter in liquid media and fermented sausage[J]. Food and Chemical Toxicology,2002,40(1):33-41.
[22]Duinker J C,Hillebrand M J. Behaviour of PCB,pentachlorobenzene,hexachlorobenzene,α-HCH,γ-HCH,β-HCH,dieldrin,endrin and p,p′-DDD in the rhinemeuse estuary and the adjacent coastal area[J]. Netherlands Journal of Sea Research,1979,13(2):256-281.
[23]krbic' B,Duriic'-Mladenovic' N. Principal component analysis for soil contamination with organochlorine compounds[J]. Chemosphere,2007,68(11):2144-2152.

相似文献/References:

[1]高亚琪,杨艺渊,地力夏提·包尔汉,等.小尺度农田生态系统土地退化监测与评价指标体系建立[J].江苏农业科学,2014,42(03):296.
 Gao Yaqi,et al.Construction of indicator system for monitoring and evaluation of land degradation of small-scale farmland ecosystem[J].Jiangsu Agricultural Sciences,2014,42(05):296.
[2]邱月,张辉.包膜氮肥、保水剂和生物炭在控制农田土壤氮素损失方面的应用综述[J].江苏农业科学,2015,43(10):417.
 Qiu Yue,et al.Application of coated fertilizer, water retention agent and biochar in controlling nitrogen loss in agricultural soil:a review[J].Jiangsu Agricultural Sciences,2015,43(05):417.
[3]夏栋,蔡崇法,龙莉,等.鄂东南花岗岩区不同崩岗侵蚀程度的农田土壤质量评价[J].江苏农业科学,2017,45(15):254.
 Xia Dong,et al.Evaluation of farmland soil quality with different collapsing erosion degree in granite area of southeastern Hubei[J].Jiangsu Agricultural Sciences,2017,45(05):254.
[4]张德喜,吴卿.不同耕作方式对农田土壤养分含量及土壤酶活性的影响[J].江苏农业科学,2018,46(11):234.
 Zhang Dexi,et al.Effects of different tillage methods on soil nutrients contents and enzyme activity in farmland[J].Jiangsu Agricultural Sciences,2018,46(05):234.
[5]程丽红,丁攀,张敏.河南省农田土壤有机氯农药残留污染特征[J].江苏农业科学,2018,46(14):247.
 Cheng Lihong,et al.Pollution characteristics of organochlorine pesticide residues in farmland soils of Henan Province[J].Jiangsu Agricultural Sciences,2018,46(05):247.
[6]王海娟,马红娜,姜海波.秸秆覆盖对塔里木盆地南缘绿洲农田土壤水盐运移的影响[J].江苏农业科学,2018,46(17):281.
 Wang Haijuan,et al.Effect of straw mulching on water and salt movement of oasis farmland on southern margin of Tarim Basin[J].Jiangsu Agricultural Sciences,2018,46(05):281.
[7]龚静静,胡宏祥,朱昌雄,等.秸秆还田对农田生态环境的影响综述[J].江苏农业科学,2018,46(23):36.
 Gong Jingjing,et al.Effect of straw turnover on farmland ecological environment: a review[J].Jiangsu Agricultural Sciences,2018,46(05):36.
[8]张慧娴,陈铁喜,江晓东,等.中国东部两熟制农田NDVI不对称年际变化趋势及其潜在气候成因[J].江苏农业科学,2019,47(08):242.
 Zhang Huixian,et al.Interannual variation trend of NDVI asymmetry in two cropping farmland in eastern China and its potential climate genesis[J].Jiangsu Agricultural Sciences,2019,47(05):242.
[9]王锦旗,宋玉芝,黄进.大气氮沉降对流域总贡献量估算方法研究[J].江苏农业科学,2020,48(11):246.
 Wang Jinqi,et al.Study on estimation method for total contribution of atmospheric nitrogen deposition to watershed[J].Jiangsu Agricultural Sciences,2020,48(05):246.
[10]张淑花,周利军,魏雅冬.施氮量对农田及防护林大型土壤动物群落结构的影响[J].江苏农业科学,2021,49(4):205.
 Zhang Shuhua,et al.Influences of nitrogen application rate on community structure of soil macrofauna in farmland and shelter forest[J].Jiangsu Agricultural Sciences,2021,49(05):205.

备注/Memo

备注/Memo:
收稿日期:2015-11-03
基金项目:湖北省科学技术项目(编号:[2015]第04181091号)。
作者简介:范钊(1982—),男,河南洛阳人,博士研究生,讲师,研究方向为环境工程、土壤及地下水保护。E-mail:fanzhao85@126.com。
更新日期/Last Update: 2016-05-25