|本期目录/Table of Contents|

[1]胡龙龙,曹勇,胡友彪.改性生物炭的制备及其环境应用进展[J].江苏农业科学,2020,48(21):46-52.
　Hu Longlong,et al.Research progress on preparation and environmental application of modified biochar[J].Jiangsu Agricultural Sciences,2020,48(21):46-52.
点击复制

改性生物炭的制备及其环境应用进展(PDF)
分享到：

《江苏农业科学》[ISSN:1002-1302/CN:32-1214/S]

卷:
第48卷
期数:
2020年21期
页码:
46-52
栏目:
专论与综述
出版日期:
2020-11-05

文章信息/Info

Title:
Research progress on preparation and environmental application of modified biochar
作者:
胡龙龙;  曹勇;  胡友彪
安徽理工大学地球与环境学院，安徽淮南 232001
Author(s):
Hu Longlong; et al
关键词:
改性生物炭; 改性方法; 生物炭制备; 环境修复; 环境风险
Keywords:
-
分类号:
TQ424.1
DOI:
-
文献标志码:
A
摘要:
生物炭因碳含量高、比表面积大、表面含有多种官能团、孔隙度发达、结构稳定等特点，越来越受到人们的重视。根据近年来已发表的文献，对改性生物炭的制备、环境应用进行了系统的分析和总结。生物炭的理化性质因原料种类、制备条件的不同而不同，对生物炭进行改性，可以显著提高其活性，增加其在环境修复中的应用潜力。生物炭可用气体活化、球磨、辐射、酸、碱、氧化剂、金属离子等处理方法进行改性，方法的选择取决于其应用领域。重点介绍了改性生物炭在土壤修复、污染水体净化、催化剂、电极材料等方面的应用研究。此外，还探讨了改性生物炭在实际应用中可能存在的问题及未来研究的主要方向，以期为改性生物炭的制备及其环境应用提供理论依据。
Abstract:
-

参考文献/References:

［1］Tan X F，Liu Y G，Zeng G M，et al. Application of biochar for the removal of pollutants from aqueous solutions［J］. Chemosphere，2015，125：70-85.
［2］Rizwan M，Ali S，Qayyum M F，et al. Mechanisms of biochar-mediated alleviation of toxicity of trace elements in plants：a critical review［J］. Environmental Science and Pollution Research，2016，23：2230-2248.
［3］Mohan D，Sarswat A，Ok Y S，et al. Organic and inorganic contaminants removal from water with biochar，a renewable，low cost and sustainable adsorbent：a critical review［J］. Bioresource Technology，2014，160：191-202.
［4］计海洋，汪玉瑛，刘玉学，等. 生物炭及改性生物炭的制备与应用研究进展［J］. 核农学报，2018，32(11)：2281-2287.
［5］Wang Y Y，Liu Y X，Lu H H，et al. Competitive adsorption of Pb(Ⅱ)，Cu(Ⅱ)，and Zn(Ⅱ) ions onto hydroxyapatite-biochar nanocomposite in aqueous solutions［J］. Journal of Solid State Chemistry，2018，261：53-61.
［6］王盛华，朱丹晨，邵敬爱，等. MgO改性莲蓬壳生物炭的制备及其磷吸附特性［J］. 环境科学，2019，40(11)：4987-4995.
［7］Lyu H H，Gao B，He F，et al. Experimental and modeling investigations of ball-milled biochar for the removal of aqueous methylene blue［J］. Chemical Engineering Journal，2018，335：110-119.
［8］Zhang Q R，Wang J M，Lyu H H，et al. Ball-milled biochar for galaxolide removal：sorption performance and governing mechanisms［J］. Science of the Total Environment，2019，659：1537-1545.
［9］Xiao Y，Lyu H H，Tang J C，et al. Effects of ball milling on the photochemistry of biochar：enrofloxacin degradation and possible mechanisms［J］. Chemical Engineering Journal，2020，384：123311.
［10］Li R H，Zhang Y C，Deng H X，et al. Removing tetracycline and Hg(Ⅱ) with ball-milled magnetic nanobiochar and its potential on polluted irrigation water reclamation［J］. Journal of Hazardous Materials，2020，384：121095.
［11］Sewu D D，Jung H，Kim S S，et al. Decolorization of cationic and anionic dye-laden wastewater by steam-activated biochar produced at an industrial-scale from spent mushroom substrate［J］. Bioresource Technology，2019，277：77-86.
［12］Kwak J H，Islam M S，Wang S Y，et al. Biochar properties and lead(Ⅱ) adsorption capacity depend on feedstock type，pyrolysis temperature，and steam activation［J］. Chemosphere，2019，231：393-404.
［13］Lam S S，Yek P N Y，Ok Y S，et al. Engineering pyrolysis biochar via single-step microwave steam activation for hazardous landfill leachate treatment［J］. Journal of Hazardous Materials，2019，390：121649.
［14］Wang R Z，Huang D L，Liu Y G，et al. Synergistic removal of copper and tetracycline from aqueous solution by steam-activated bamboo-derived biochar［J］. Journal of Hazardous Materials，2020，384：121470.
［15］Paunovic O，Pap S，Maletic S，et al. Ionisable emerging pharmaceutical adsorption onto microwave functionalised biochar derived from novel lignocellulosic waste biomass［J］. Journal of Colloid and Interface Science，2019，547：350-360.
［16］李桥，雍毅，丁文川，等. 紫外辐照改性生物炭对 VOCs 的动态吸附［J］. 环境科学，2016，37(6)：2065-2072.
［17］Zhang J J，Shao J G，Jin Q Z，et al. Sludge-based biochar activation to enhance Pb(Ⅱ) adsorption［J］. Fuel，2019，252：101-108.
［18］丁文川，权国卿，曾晓岚，等. 紫外辐照引入含氧官能团对生物炭吸附气体和水中苯的影响［J］. 环境科学学报，2017，37(2)：657-663.
［19］朱银涛. 生物炭改性制备及其对重金属Zn钝化效果的初步研究［D］. 长春：吉林农业大学，2018.
［20］Wang J L，Wang S Z. Preparation，modification and environmental application of biochar：a review［J］. Journal of Cleaner Production，2019，227：1002-1022.
［21］Rajapaksha A U，Vithanage M，Zhang M，et al. Pyrolysis condition affected sulfamethazine sorption by tea waste biochars［J］. Bioresource Technology，2014，166：303-308.
［22］Kim Y，Oh J I，Vithanage M，et al. Modification of biochar properties using CO2［J］. Chemical Engineering Journal，2019，372：383-389.
［23］Shan D N，Deng S B，Zhao T N，et al. Preparation of ultrafine magnetic biochar and activated carbon for pharmaceutical adsorption and subsequent degradation by ball milling［J］. Journal of Hazardous Materials，2016，305：156-163.
［24］Lyu H H，Gao B，He F，et al. Effects of ball milling on the physicochemical and sorptive properties of biochar：Experimental observations and governing mechanisms［J］. Environmental Pollution，2018，233：54-63.
［25］李桥，高屿涛，姜蔚，等. 紫外辐照改性生物炭对土壤中Cd的稳定化效果［J］. 环境工程学报，2017，11(10)：5708-5714.
［26］Wang B，Gao B，Fang J. Recent advances in engineered biochar productions and applications［J］. Critical Reviews in Environmental Science and Technology，2018，7：2158-2207.
［27］Maek O，Budarin V，Gronnow M，et al. Microwave and slow pyrolysis biochar-Comparison of physical and functional properties［J］. Journal of Analytical and Applied Pyrolysis，2013，100：41-48.
［28］Goswami R，Shim J，Deka S，et al. Characterization of cadmium removal from aqueous solution by biochar produced from Ipomoea fistulosa at different pyrolytic temperatures［J］. Ecological Engineering，2016，97：444-451.
［29］Jin H M，Capared S，Chang Z Z，et al. Biochar pyrolytically produced from municipal solid wastes for aqueous As(V) removal：sorption property and its improvement with KOH activation［J］. Bioresource Technology，2014 169：622-629.
［30］高超群. 生物炭及其改性材料对铅的吸附研究［D］. 西安：长安大学，2018.
［31］Jin H M，Hanif M U，Capareda S，et al. Copper(Ⅱ) removal potential from aqueous solution by pyrolysis biochar derived from anaerobically digested algae-dairy-manure and effect of KOH activation［J］. Journal of Environmental Chemical Engineering，2016，4(1)：365-372.
［32］Cheng D L，Ngo H H，Guo W S，et al. Feasibility study on a new pomelo peel derived biochar for tetracycline antibiotics removal in swine wastewater［J］. Science of the Total Environment，2020，720：137662.
［33］An Q，Jiang Y Q，Nan H Y，et al. Unraveling sorption of nickel from aqueous solution by KMnO4 and KOH-modified peanut shell biochar：implicit mechanism［J］. Chemosphere，2019，214：846-854.
［34］Jin J，Li S W，Peng X Q，et al. HNO3 modified biochars for uranium (VI) removal from aqueous solution［J］. Bioresource Technology，2018，256：247-253.
［35］Zuo X J，Liu Z G，Chen M D. Effect of H2O2 concentrations on copper removal using the modified hydrothermal biochar［J］. Bioresource Technology，2016，207：262-267.
［36］Shen B X，Liu Z，Xu H，et al. Enhancing the absorption of elemental mercury using hydrogen peroxide modified bamboo carbons［J］. Fuel，2019，235：878-885.
［37］Shen W Z，Li Z J，Liu Y H. Surface chemical functional groups modification of porous carbon［J］. Recent Patents on Chemical Engineering，2008，1 (1)：27-40.
［38］Chen T W，Luo L，Deng S H，et al. Sorption of tetracycline on H3PO4 modified biochar derived from rice straw and swine manure［J］. Bioresource Technology，2018，267：431-437.
［39］Ma Y，Liu W J，Zhang N，et al. Polyethylenimine modified biochar adsorbent for hexavalent chromium removal from the aqueous solution［J］. Bioresource Technology，2014，169：403-408.
［40］Feng Z J，Zhu L Z. Sorption of phenanthrene to biochar modified by base［J］. Frontiers of Environmental Science & Engineering，2018，12(2)：5-15.
［41］Huff M D，Lee J W. Biochar-surface oxygenation with hydrogen peroxide［J］Journal of Environmental Management，2016，165：17-21.
［42］Tan X F，Liu Y G，Gu Y L，et al. Biochar-based nano-composites for the decontamination of wastewater：a review［J］. Bioresource Technology，2016，212：318-333.
［43］Ajmal Z，Muhmood A，Dong R J，et al. Probing the efficiency of magnetically modified biomass-derived biochar for effective phosphate removal［J］. Journal of Environmental Management，2020，253：109730.
［44］赵旭，王淑娟，郭伟，等. 磁性稻壳生物炭对水体中菲的去除特性［J］. 水资源保护，2019，35(5)：70-77.
［45］易鹏，吴国娟，段文焱，等. 生物炭的改性和老化及环境效应的研究进展［J］. 材料导报，2020，34(3)：37-43.
［46］张慧. 炭化秸秆对水体中氨氮、磷的去除效果研究［D］. 南京：南京农业大学，2009.
［47］Yao Y，Zhang Y，Gao B，et al. Removal of sulfamethoxazole (SMX) and sulfapyridine (SPY) from aqueous solutions by biochars derived from anaerobically digested bagasse［J］. Environmental Science and Pollution Research，2018，25(26)：25659-25667.
［48］Tao Q，Chen Y X，Zhao J W，et al. Enhanced Cd removal from aqueous solution by biologically modified biochar derived from digestion residue of corn straw silage［J］. Science of the Total Environment，2019，674：213-222.
［49］Ahmed M B，Zhou J L，Ngo H H，et al.Progress in the preparation and application of modified biochar for improved contaminant removal from water and wastewater［J］. Bioresource Technology，2016，214：836-851.
［50］Wang S S，Gao B，Zimmerman A R，et al. Removal of arsenic by magnetic biochar prepared from pinewood and natural hematite［J］. Bioresource Technology，2015，175：391-395.
［51］朱司航，赵晶晶，尹英杰，等. 针铁矿改性生物炭对砷吸附性能［J］. 环境科学，2019，40(6)：2773-2782.
［52］徐大勇，张苗，杨伟伟，等. 氧化铝改性污泥生物炭粒制备及其对Pb(Ⅱ)的吸附特性［J］. 化工进展，2020，39(3)：1153-1166.
［53］Ma Y，Liu W J，Zhang N，et al. Polyethylenimine modified biochar adsorbent for hexavalent chromium removal from the aqueous solution［J］. Bioresource Technology，2014，169：403-408.
［54］朱司航，赵晶晶，楚龙港，等. 纳米羟基磷灰石改性生物炭对铜的吸附性能研究［J］. 农业环境科学学报，2017，36(10)：2092-2098.
［55］张连科，王洋，王维大，等. 磁性羟基磷灰石/生物炭复合材料的制备及对Pb2+的吸附性能［J］. 环境科学学报，2018，38(11)：4360-4370.
［56］李三姗，王楚楚，何晓云，等. 改性水生植物生物炭对低浓度硝态氮的吸附特性［J］. 生态与农村环境学报，2018，34(4)：356-362.
［57］Wang Y Y，Ji H Y，Lu H H，et al. Simultaneous removal of Sb(Ⅲ) and Cd(Ⅱ) in water by adsorption onto a MnFe2O4-biochar nanocomposite［J］. RSC Advances，2018，8(6)：3264-3273.
［58］Wongrod S，Simon S，Guibaud G，et al. Lead sorption by biochar produced from digestates：consequences of chemical modification and washing［J］. Journal of Environmental Management，2018，219：227-284.
［59］Li C J，Zhang L，Gao Y，et al. Facile synthesis of nano ZnO/ZnS modified biochar by directly pyrolyzing of zinc contaminated corn stover for Pb(Ⅱ)，Cu(Ⅱ) and Cr(Ⅵ) removals［J］. Waste Management，2018，79：625-637.
［60］He R Z，Peng Z Y，Lyu H H，et al. Synthesis and characterization of an iron-impregnated biochar for aqueous arsenic removal［J］. Science of the Total Environment，2018，612：1177-1186.
［61］Pan J J，Jiang J，Xu R K. Removal of Cr(Ⅵ) from aqueous solutions by Na2SO4/FeSO4 combined with peanut straw biochar［J］. Chemosphere，2014，101：71-76.
［62］Yuan P，Wang J Q，Pan Y J，et al. Review of biochar for the management of contaminated soil：preparation，application and prospect［J］. Science of the Total Environment，2019，659：473-490.
［63］OConnor D，Peng T Y，Li G H，et al. Sulfur-modified rice husk biochar：a green method for the remediation of mercury contaminated soil［J］. Science of the Total Environment，2018，621：819-826.
［64］Xia Y，Liu H J，Guo Y C，et al. Immobilization of heavy metals in contaminated soils by modified hydrochar：efficiency，risk assessment and potential mechanisms［J］. Science of the Total Environment，2019，685：1201-1208.
［65］毕景望，单锐，韩静，等. 改性西瓜皮生物炭的制备及其对Pb(Ⅱ)的吸附特性［J］. 环境科学，2020，41(4)：1770-1778.
［66］Gao R L，Fu Q L，Hu H Q，et al. Highly-effective removal of Pb by co-pyrolysis biochar derived from rape straw and orthophosphate［J］. Journal of Hazardous Materials，2019，371：191-197.
［67］Mortazavian S，Jones-Lepp T，Bae J H，et al. Heat-treated biochar impregnated with zero-valent iron nanoparticles for organic contaminants removal from aqueous phase：material characterizations and kinetic studies［J］. Journal of Industrial and Engineering Chemistry，2019，76：197-214.
［68］Park J H，Wang J J.，Xiao R，et al. Degradation of Orange G by Fenton-like reaction with Fe-impregnated biochar catalyst［J］. Bioresource Technology，2018，249：368-376.
［69］Wan C C，Jiao Y，Li J. Core-shell composite of wood-derived biochar supported MnO2 nanosheets for supercapacitor applications［J］. RSC Advances，2016，6(69)：64811-64817.
［70］Wang C Y，Wang Y D，Herath H M S K. Polycyclic aromatic hydrocarbons (PAHs) in biochar-their formation，occurrence and analysis：a review［J］. Organic Geochemistry，2017，114：1-14.
［71］Rechberger M V，Kloss S，Wang S L，et al. Enhanced Cu and Cd sorption after soil aging of woodchip-derived biochar：what were the driving factors？［J］. Chemosphere，2019，216：463-471.
［72］周丹丹，吴文卫，吴敏. 生物炭的稳定性及其评价方法［J］. 重庆大学学报(自然科学版)，2015，38(3)：116-122.
［73］Kaal J，Cortizas M A，Nierop K G J. Characterisation of aged charcoal using a coil probe pyrolysis-GC/MS method optimised for black carbon［J］. Journal of Analytical and Applied Pyrolysis，2009，85(1/2)：408-416.
［74］Kuzyakov Y，Bogomolova I，Glaser B. Biochar stability in soil：decomposition during eight years and transformation as assessed by compound-specific 14C analysis［J］. Soil Biology and Biochemistry，2014，70：229-236.

相似文献/References:

[1]彭杨,贺峦,高学鹏,等.生物炭负载纳米氧化锌对复合污染油茶生理生化、元素吸收及土壤性质的影响[J].江苏农业科学,2024,52(19):180.
　Peng Yang,et al.Effects of biochar-loaded nano-zinc oxide on physiology，biochemistry，element absorption and soil properties of Camellia oleifera in combined pollution[J].Jiangsu Agricultural Sciences,2024,52(21):180.
[2]罗玉博,吕鑫航,刘文彬,等.镁改性生物炭对酸化茶园土壤的改良效果[J].江苏农业科学,2025,53(6):231.
　Luo Yubo,et al.Ameliorative effects of magnesium-modified biochar on acidified tea plantation soil[J].Jiangsu Agricultural Sciences,2025,53(21):231.

备注/Memo

备注/Memo:
收稿日期：2020-04-07
基金项目：国家自然科学基金青年科学基金(编号：41601340)。
作者简介：胡龙龙(1994—)，男，安徽淮南人，硕士研究生，主要研究方向为土壤重金属污染修复。E-mail：17865932508@163.com。
通信作者：胡友彪，博士，教授，主要研究方向为矿区生态环境修复。E-mail：ybhu@aust.edu.cn。
更新日期/Last Update: 2020-11-05