|本期目录/Table of Contents|

[1]张玉涛,李琪琪,张晓娟,等.汞离子与土壤富里酸的络合反应及影响因素[J].江苏农业科学,2017,45(21):272-274.
 Zhang Yutao,et al.Complex reaction of mercury ion and soil fulvic acid and its influencing factors[J].Jiangsu Agricultural Sciences,2017,45(21):272-274.
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汞离子与土壤富里酸的络合反应及影响因素(PDF)
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《江苏农业科学》[ISSN:1002-1302/CN:32-1214/S]

卷:
第45卷
期数:
2017年第21期
页码:
272-274
栏目:
资源与环境
出版日期:
2017-11-05

文章信息/Info

Title:
Complex reaction of mercury ion and soil fulvic acid and its influencing factors
作者:
张玉涛12 李琪琪1 张晓娟12 陈红亮12 张秋云12 魏方方1 何映霞2
1.安顺学院化学化工学院,贵州安顺 561000; 2.安顺学院/贵州省科技厅土壤污染控制与修复工程技术中心,贵州安顺 561000
Author(s):
Zhang Yutaoet al
关键词:
富里酸络合反应影响因素
Keywords:
-
分类号:
X131
DOI:
-
文献标志码:
A
摘要:
汞是一种对环境危害极大的重金属污染物,天然有机质对汞的地球化学循环有重要影响。通过离子选择性电极法测定富里酸与汞离子络合条件的稳定常数为lgk=4.86,同时,对总汞浓度、pH值、离子强度等因素对络合率的影响进行了评估。结果显示,总汞浓度可促进络合反应的进行,络合率随溶液pH值的升高而增大,而离子强度对络合反应则呈抑制作用。
Abstract:
-

参考文献/References:

[1]Bloom N. Determination of picogram levels of methylmercury by aqueous phase ethylation,followed by cryogenic gas-chromatography with cold vapor atomic fluorescence detection[J]. Canadian Journal of Fisheries and Aquatic Sciences,1989,46(7):1131-1140.
[2]Mason R P,Benoit J M. Organo mercury compounds in the environment[M]. 2nd ed. Chichester:John Wiley and Sons,Ltd,2003:57-99.
[3]Savery L C,Evers D C,Wise S S,et al. Global mercury and Selenium concentrations in skin from free-ranging sperm whales (Physeter macrocephalus)[J]. Science of the Total Environment,2013,450-451:59-71.
[4]Haitzer M,Aiken G R,Ryan J N. Binding of mercury(Ⅱ) to dissolved organic matter:the role of the mercury-to-DOM concentration ratio[J]. Environmental Science & Technology,2002,36(16):3564-3570.
[5]Lindqvist O,Johansson K,Bringmark L,et al. Mercury in the Swedish environment-recent research on causes,consequences and corrective methods,water air soil pollut[J]. Water,Air,and Soil Pollution,1991,55(1/2):1-261.
[6]Hudson R J M,Gherini S A,Watras C J,et al. Modeling the biogeochemical cycle of mercury in lakes:the mercury cycling model(MCM)and its application to the MTL study lakes[M]. Boca Raton:Lewis Publishers,1994:473-523.
[7]赵士波,孙荣国,王定勇,等. 低分子有机酸对汞氧化还原反应的影响[J]. 环境科学,2014,35(6):2193-2200.
[8]游蕊,梁丽,覃蔡清,等. 低分子量有机酸对三峡水库消落区土壤中汞赋存形态及其活性的影响[J]. 环境科学,2016,37(1):173-179.
[9]Cai Y,Jaff R,Jones R D. Interactions between dissolved organic carbon and mercury species in surface waters of the Florida Everglades[J]. Applied Geochemistry,1999,14(3):395-407.
[10]Si L,Ariya P A. Reduction of oxidized mercury species by dicarboxylic acids (C2-C4):kinetic and product studies[J]. Environmental Science & Technology,2008,42(14):5150-5155.
[11]Chin Y P,Aiken G,OLoughlin E W,et al. Molecular weight,polydispersity,and spectroscopic properties of aquatic humic substances[J]. Environmental Science & Technology,1994,28(11):1853-1858.
[12]陈春羽,王定勇. 水溶性有机质对土壤及底泥中汞吸附行为的影响[J]. 环境科学学报,2009,29(2):312-317.
[13]Zhang Y,Chen X,Yang Y,et al. Effect of dissolved organic matter on mercury release from water body[J]. Journal of Environmental Sciences,2011,23(6):912-917.
[14]Rolfhus K R,Fitzgerald W M. The evasion and spatial/temporal distribution of mercury species in Long Island Sound,CT-NY[J]. Geochimica et Cosmochimica acta,2001,65(3):407-418.
[15]Odriscoll N J,Beauchamp S,Siciliano S D,et al. Continuous analysis of dissolved gaseous mercury (DGM) and mercury flux in two freshwater lakes in Kejimkujik park,Nova Scotia:evaluating mercury flux models with quantitative data[J]. Environmental Science & Technology,2003,37(10):2226-2235.
[16]翟莹雪. 富里酸与几种金属离子的相互作用及影响因素研究[D]. 重庆:西南农业大学,2003.
[17]潘波,曹军,刘国敬,等. 鲤鱼鱼鳃黏液对铜的络合特征[J]. 环境化学,2002,21(3):245-249.
[18]Strohal P,Hulijev D. Investigation of mercury pollutant interaction with humic acids by means of radiotracers[J/OL]. [2017-03-01]. http://www.researchgate.net/publication/313085938_Investigation_of_mercuty_pollutant_interaction_with_humic_acids_by_means_of_radiotracers..
[19]Cheam V,Gamble D S. Metal-fulvic acid chelation equilibrium in aqueous NaNO3 solution.Hg(Ⅱ),Cd(Ⅱ),and Cu(Ⅱ)fulvate complexes[J]. Canadian Journal of Soil Science,1974,54(4):413-417.
[20]Yin Y J,Alien H E,Huang C P,et al. Interaction of Hg(Ⅱ) with soil-derived humic substances[J]. Analytica Chimica Acta,1997,341(1):73-82.
[21]Skyllberg U,Bloom P R,Nater E A,et al. Complexation of Hg(Ⅱ)by reduced sulfur in soil organic matter[J]. Humus-Nordic Humus Newsletter,1997(4):11-12.
[22]Skyllberg U,Xia K,Bloom P R,et al. Binding of mercury(Ⅱ)to reduced sulfur in soil organic matter along upland-peat soil transects[J]. Journal of Environmental Quality,2000,29(3):855-865.
[23]Mantoura R F C,Riley J P. The use of gel filtration in the study of metal binding by humic acids and related compounds[J]. Analytica Chimica Acta,1975,78(1):193-200.
[24]Benoit J M,Mason R P,Gilmour C C,et al. Constants for mercury binding by dissolved organic matter isolates from the Florida Everglades[J]. Geochimica et Cosmochimica Acta,2001,65(24):4445-4451.
[25]Lamborg C H,Tseng C M,Fitzgerald W F,et al. Determination of the mercury complexation characteristics of dissolved organic matter in natural waters with “reducible Hg” titrations[J]. Environmental Science & Technology,2003,37(15):3316-3322.
[26]Hsu H,Sedlak D L. Strong Hg(Ⅱ) complexation in municipal wastewater effluent and surface waters[J]. Environmental Science & Technology,2003,37(12):2743-2749.
[27]曹军,李本纲,徐福留,等. 水体与土壤中天然有机物与铜的络合作用及其影响因素[J]. 环境科学学报,2001,21(6):726-730.
[28]李丽,宋姚,侯娟娟,等. 铜离子选择性电极法研究腐殖酸与铜离子络合的影响因素[J]. 环保科技,2010,16(1):23-25.

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备注/Memo

备注/Memo:
收稿日期:2017-03-27
基金项目:国家自然科学基金(编号:41403114);贵州省科技厅三方联合基金(编号:黔科合LH字[2016]7278);安顺市科技创新平台建设计划(编号:安市科平[2016]4号)。
作者简介:张玉涛(1979—),男,山东济宁人,博士,教授,从事环境污染物迁移转化研究。E-mail:zyt0516@126.com。
更新日期/Last Update: 2017-11-05