|本期目录/Table of Contents|

[1]张建刚,谢晋鹏,张丽,等.利用MALDI-TOFMS检测农药的新方法[J].江苏农业科学,2017,45(17):172-175.
　Zhang Jiangang,et al.A new method for detecting pesticides contents by MALDI-TOFMS[J].Jiangsu Agricultural Sciences,2017,45(17):172-175.
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《江苏农业科学》[ISSN:1002-1302/CN:32-1214/S]

卷:
第45卷
期数:
2017年17期
页码:
172-175
栏目:
贮藏加工与检测分析
出版日期:
2017-09-05

文章信息/Info

Title:
A new method for detecting pesticides contents by MALDI-TOFMS
作者:
张建刚1;  谢晋鹏1;  张丽1;  赵晋忠1;  马望京2
1.山西农业大学文理学院，山西晋中 030801； 2.中国科学院理化技术研究所，北京 100080
Author(s):
Zhang Jiangang; et al
关键词:
MALDI-TOFMS; 农药; 检测方法; 温和氧化石墨烯
Keywords:
-
分类号:
S481+.8
DOI:
-
文献标志码:
A
摘要:
以新合成的温和氧化石墨烯为基质，成功实现了用基质协助激光解吸离子飞行时间质谱(MALDI-TOFMS)的方法对阿克泰、高效氯氰菊酯、残杀威、吡虫啉、猛杀威、乐果等6种农药的检测，得到良好的检测特征图谱，成功地避免了用MALDI-TOFMS检测农药等小分子时的基质干扰，探索了快速检测农药的新方法，同时也为其他痕量有机污染物的检测提供了新思路。
Abstract:
-

参考文献/References:

［1］Zhang J G，Zhang L，Li R，et al. Magnetic graphene composites as both an adsorbent for sample enrichment and a MALDI-TOFMS matrix for the detection of nitropolycyclic aromatic hydrocarbons in PM2.5［J］. Analyst，2015，140(5)：1711-1716.
［2］Rivas D，Ginebreda A，Pérez S，et al. MALDI-TOFMS imaging evidences spatial differences in the degradation of solid polycaprolactone diol in water under aerobic and denitrifying conditions［J］. Science of the Total Environment，2016，566-567：27-33.
［3］Soltzberg L J，Patel P. Small molecule matrix-assisted laser desorption/ionization time-of-flight mass spectrometry using a polymer matrix［J］. Rapid Communications in Mass Spectrometry，2004，18(13)：1455-1458.
［4］Wei J，Buriak J M，Siuzdak G. Desorption-ionization mass spectrometry on porous silicon［J］. Nature，1999，399(6733)：243-246.
［5］Lewis W G，Shen Z，Finn M G，et al. Desorption/ionization on silicon (DIOS) mass spectrometry：background and applications［J］. International Journal of Mass Spectrometry，2003，226(1)：107-116.
［6］Zhang Q C，Zou H F，Guo Z，et al. Matrix‐assisted laser desorption/ionization mass spectrometry using porous silicon and silica gel as matrix［J］. Rapid Communications in Mass Spectrometry，2001，15(3)：217-223.
［7］Zou H F，Zhang Q C，Guo Z，et al. A mass spectrometry based directbinding assay for screening binding partners of proteins［J］. Angewandte Chemie International Edition，2002，41(4)：646-648.
［8］Guo Z，Zhang Q C，Zou H F，et al. A method for the analysis of low-mass molecules by MALDI-TOF mass spectrometry［J］. Analytical Chemistry，2002，74(7)：1637-1641.
［9］Gholipour Y，Giudicessi S L，Nonami H，et al. Diamond，titanium dioxide，titanium silicon oxide，and barium strontium titanium oxide nanoparticles as matrixes for direct matrix-assisted laser desorption/ionization mass spectrometry analysis of carbohydrates in plant tissues［J］. Analytical Chemistry，2010，82(13)：5518-5526.
［10］Lorkiewicz P，Yappert M C. Titania microparticles and nanoparticles as matrixes for in vitro and in situ analysis of small molecules by MALDI-MS［J］. Analytical Chemistry，2009，81(16)：6596-6603.
［11］Castro A L，Madeira P J A，Nunes M R，et al. Titanium dioxide anatase as matrix for matrix-assisted laser desorption/ionization analysis of small molecules［J］. Rapid Communications in Mass Spectrometry，2008，22(23)：3761-3766.
［12］Castro A L，Madeira P J A，Nunes M R，et al. Titanium dioxide anatase as matrix for matrix-assisted laser desorption/ionization analysis of small molecules［J］. Rapid Communications in Mass Spectrometry，2008，22(23)：3761-3766.
［13］Rainer M，Najam-UL-Haq M，Huck C W，et al. Carbon based sample supports and matrices for laser desorption/ionization mass spectrometry［J］. Recent Patents on Nanotechnology，2007，1(2)：113-119.
［14］Sunner J，Dratz E，Chen Y C. Graphite surface-assisted laser desorption/ionization time-of-flight mass spectrometry of peptides and proteins from liquid solutions［J］. Analytical Chemistry，1995，67(23)：4335-4342.
［15］Han M，Sunner J. An activated carbon substrate surface for laser desorption mass spectrometry［J］. Journal of the American Society for Mass Spectrometry，2000，11(7)：644-649.
［16］Xu S Y，Li Y F，Zou H F，et al. Carbon nanotubes as assisted matrix for laser desorption/ionization time-of-flight mass spectrometry［J］. Analytical Chemistry，2003，75(22)：6191-6195.
［17］Pumera M. Electrochemistry of graphene：new horizons for sensing and energy storage［J］. The Chemical Record，2009，9(4)：211-223.
［18］Kim K S，Zhao Y，Jang H，et al. Large-scale pattern growth of graphene films for stretchable transparent electrodes［J］. Nature，2009，457(7230)：706-710.
［19］李惠茗，张惠怡，赖祥文，等. 鞣酸功能化石墨烯修饰电极上芦丁的电化学行为及灵敏检测［J］. 分析测试学报，2016，35(3)：292-298.

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备注/Memo

备注/Memo:
收稿日期：2017-03-20
基金项目：中国博士后科学基金(编号：2016M591410)；中国科学院光化学转换与功能材料重点实验室开放基金；山西农业大学博士启动基金(编号：2014ZZ03)。
作者简介：张建刚(1978—)，男，山西晋中人，博士，副教授，主要从事环境分析化学和农药残留检测方面的研究。E-mail：zjg487992@163.com。
更新日期/Last Update: 2017-09-05