|本期目录/Table of Contents|

[1]乐渊,邓正敏,刘春华,等.多壁碳纳米管净化-超高效液相色谱串联质谱法测定香蕉中8种新烟碱类杀虫剂[J].江苏农业科学,2020,48(04):181-186.
　Le Yuan,et al.Determination of eight neonicotinoid insecticides residues in banana using ultra-performance liquid chromatography-tandem mass spectrometry coupled with multiwalled carbon nanotubes purification[J].Jiangsu Agricultural Sciences,2020,48(04):181-186.
点击复制

多壁碳纳米管净化-超高效液相色谱串联质谱法
测定香蕉中8种新烟碱类杀虫剂(PDF)
分享到：

《江苏农业科学》[ISSN:1002-1302/CN:32-1214/S]

卷:
第48卷
期数:
2020年第04期
页码:
181-186
栏目:
贮藏加工与检测分析
出版日期:
2020-03-25

文章信息/Info

Title:
Determination of eight neonicotinoid insecticides residues in banana using ultra-performance liquid chromatography-tandem mass spectrometry coupled with multiwalled carbon nanotubes purification
作者:
乐渊;  邓正敏;  刘春华;  吴南村
中国热带农业科学院分析测试中心/海南省热带果蔬产品质量安全重点实验室，海南海口 571101
Author(s):
Le Yuan; et al
关键词:
香蕉; 新烟碱类杀虫剂; 多壁碳纳米管; 超高效液相色谱-串联质谱; 加标回收率; 残留量
Keywords:
-
分类号:
S481+.8
DOI:
-
文献标志码:
A
摘要:
建立基于多壁碳纳米管净化、超高效液相色谱串联质谱技术同时测定香蕉中呋虫胺等8种新烟碱类杀虫剂残留量的分析方法。香蕉样品中用含1%乙酸的乙腈提取后，经多壁碳纳米管净化后，用超高效液相色谱-串联质谱法测定。呋虫胺等8种新烟碱类杀虫剂的质量浓度在0.005~0.200 mg/L范围内线性良好，最低检出限在0.03～0.44 μg/kg 之间，相关系数均大于0.99，平均加标回收率在75.2%~114.9%之间，相对标准差在0.3%~9.5%之间。与N-丙基乙二胺和石墨化碳黑吸附剂相比，多壁碳纳米管具有净化效果好和效率高等优点。方法学考察及实际样品的测定证明该方法简便、快速、准确，可用于香蕉中呋虫胺等8种新烟碱类杀虫剂残留量的检测。
Abstract:
-

参考文献/References:

［1］Goulson D. Review：an overview of the environmental risks posed by neonicotinoid insecticides［J］. Journal of Applied Ecology，2013，50(4)：977-987.
［2］李强，付步礼，邱海燕，等. 滴灌施药技术防治香蕉黄胸蓟马应用展望［J］. 农学学报，2018，8(4)：14-18.
［3］Poulsen M E，Andersen J H，Petersen A，et al. Results from the Danish monitoring programme for pesticide residues from the period 2004—2011［J］. Food Control，2017，74：25-33.
［4］Tosi S，Burgio G，Nieh J C. A common neonicotinoid pesticide，thiamethoxam，impairs honey bee flight ability［J］. Scientific Reports，2017，7(1)：1201.
［5］袁锐，李丽莉，李超，等. 六种新烟碱类杀虫剂对凹唇壁蜂的毒性及风险评估［J］. 昆虫学报，2018，61(8)：950-956.
［6］李田田，郑珊珊，王晶，等. 新烟碱类农药的污染现状及转化行为研究进展［J］. 生态毒理学报，2018，13(4)：9-21.
［7］Anastassiades M，Lehotay S J，Stajnbaher D，et al. Fast and easy multi-residue method employing acetonitrile extraction/partitioning an“dispersive solid-phase extraction”for the determination of pesticide residues in produce［J］. Journal of AOAC International，2003，86(2)：412-431.
［8］Hou X，Lei S，Qiu S，et al. A multi-residue method for the determination of pesticides in tea using multi-walled carbon nanotubes as a dispersive solid phase extraction absorbent［J］. Food Chemistry，2014，153：121-129.
［9］Jakubus A，Tyma M，Stepnowski P，et al. Application of passive sampling devices based on multi-walled carbon nanotubes for the isolation of selected pharmaceuticals and phenolic compounds in water samples - possibilities and limitations［J］. Talanta，2017，164：700-707.
［10］Han Z，Jiang K，Fan Z，et al. Multi-walled carbon nanotubes-based magnetic solid-phase extraction for the determination of zearalenone and its derivatives in maize by ultra-high performance liquid chromatography-tandem mass spectrometry［J］. Food Control，2017，79：177-184.
［11］Lehotay S J. Determination of pesticide residues in foods by acetonitrile extraction and partitioning with magnesium sulfate：collaborative study［J］. Journal of AOAC International，2007，90(2)：485-520.
［12］Foods of plant origin-Determination of pesticide residues using GC-MS and/or LC-MS/MS following acetonitrile extraction/partitioning and clean-up by dispersive SPE-QuEChERS-method：European Standard EN 15662［S］. Brussels：Europe and Committee for Standardization，2008.
［13］田海英，韦凤杰，张东豫，等. RP-HPLC法测定烟草中的质体色素［J］. 烟草科技，2009(4)：32-36.
［14］农药残留试验准则：NY/T 788—2004［S］. 北京：中国农业出版社，2004.
［15］Kruve A，Künnapas A，Herodes K，et al. Matrix effects in pesticide multi-residue analysis by liquid chromatography-mass spectrometry［J］. Journal of Chromatography A，2008，1187(1/2)：58-66.
［16］刘进玺，秦珊珊，冯书惠，等. 高效液相色谱-串联质谱法测定食用菌中农药多残留的基质效应［J］. 食品科学，2016，37(18)：171-177.
［17］Garrido F A，Martínez V J L，Fernández M J L，et al. Compensation for matrix effects in gas chromatography-tandem mass spectrometry using a single point standard addition［J］. Journal of Chromatography A，2009，1216(23)：4798-4808.
［18］Martínez-Galera M，López-López T，Gil-García M D，et al. A comparative study of the correction of systematic errors in the quantitation of pyrethroids in vegetables using calibration curves prepared using standards in pure solvent［J］. Analytical and Bioanalytical Chemistry，2003，375(5)：653-660.
［19］食品安全国家标准食品中农药残留最大限量：GB 2763—2016［S］. 北京：中国标准出版社，2017.

相似文献/References:

[1]纪韦韦,朱雅君,宋青.辐照检疫处理对香蕉货架品质的影响[J].江苏农业科学,2014,42(12):309.
　Ji Weiwei,et al.Effect of quarantine radiation treatment on quality of banana in shelf life[J].Jiangsu Agricultural Sciences,2014,42(04):309.
[2]苏布道,金冻栋.荸荠皮壳聚糖复合提取液对香蕉的保鲜作用[J].江苏农业科学,2015,43(07):291.
　Su Budao,et al.Fresh-keeping effect of compound extract of chitosan from Eleocharis tuberosa peel on banana[J].Jiangsu Agricultural Sciences,2015,43(04):291.
[3]赵 艳,张晓波,阮云泽,等.海南省不同地区香蕉根结线虫病的种类及发生情况[J].江苏农业科学,2015,43(02):128.
　Zhao Yan,et al.Species and occurrence of banana root-knot nematode in different areas of Hainan Province[J].Jiangsu Agricultural Sciences,2015,43(04):128.
[4]黄丽娜,赵志汝,程世敏,等.交联聚丙烯酰胺配施尿素对香蕉苗期生长及氮素去向的影响[J].江苏农业科学,2016,44(10):218.
　Huang Lina,et al.Effects of combined application of crosslinked polyacrylamide and urea on seedling growth and nitrogen fate of banana[J].Jiangsu Agricultural Sciences,2016,44(04):218.
[5]顾天竹,周启凡.中国香蕉生产布局的时空演变分析[J].江苏农业科学,2017,45(05):315.
　Gu Tianzhu,et al.Spatial and temporal evolution of Chinas banana production[J].Jiangsu Agricultural Sciences,2017,45(04):315.
[6]朱莉,李远颂,尹学琼.壳聚糖-茶树油复合保鲜液对香蕉的保鲜效果[J].江苏农业科学,2017,45(15):167.
　Zhu Li,et al.Fresh preservation of bananas with chitosan-tea tree oil composite solution[J].Jiangsu Agricultural Sciences,2017,45(04):167.
[7]王海波,李璐,苏新国,等.MaCaM和MaCAMTA3基因在热处理诱导香蕉抗冷性中的作用[J].江苏农业科学,2018,46(05):40.
　Wang Haibo,et al.Role of MaCaM and MaCAMTA3 genes in heat treatment-induced chilling tolerance of banana fruit[J].Jiangsu Agricultural Sciences,2018,46(04):40.
[8]李璐,张昭其,庞学群,等.CBF冷信号通路基因在热处理诱导的香蕉抗病性中的作用[J].江苏农业科学,2018,46(07):193.
　Li Lu,et al.Role of CBF cold response pathway gene in heat treatment-induced disease tolerance of banana[J].Jiangsu Agricultural Sciences,2018,46(04):193.
[9]龙玲,李勇,严煌倩,等.小松菜对土壤中4种新烟碱类杀虫剂的吸收转运差异[J].江苏农业科学,2018,46(07):205.
　Long Ling,et al.Differences of uptake and translocation of four neonicotinoids in komatsuna[J].Jiangsu Agricultural Sciences,2018,46(04):205.
[10]赵小云,谢德芳.超高效液相色谱-串联质谱对香蕉中苯醚甲环唑和噻呋酰胺农药残留的检测[J].江苏农业科学,2019,47(02):181.
　Zhao Xiaoyun,et al.Detection of difenoconazole and thifluzamide residue in banana using ultra performance liquid chromatography-tandem mass spectrometry[J].Jiangsu Agricultural Sciences,2019,47(04):181.

备注/Memo

备注/Memo:
收稿日期：2018-11-22
基金项目：现代农业产业技术体系建设专项(编号：CARS-31-13)；热带农产品质量安全科技创新团队项目(编号：1630082017002)。
作者简介：乐渊(1985—)，男，江西抚州人，硕士，助理研究员，主要从事农产品质量安全研究。E-mail：leyuan06@sina.com。
更新日期/Last Update: 2020-02-20